Size Fractionation (Dissolved, Colloidal and Particulate) of Trace Metals in the Thur River, Switzerland     

Laura Sigg  Hanbin Xue  David Kistler  René Sshönenberger 《Aquatic Geochemistry》2000,6(4):413-434

The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L^-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions.  相似文献   

Lucinid clam influence on the biogeochemistry of the seagrass<Emphasis Type="Italic">Thalassia testudinum</Emphasis> sediments     

Laura K. Reynolds  Peter Berg  Joseph C. Zieman 《Estuaries and Coasts》2007,30(3):482-490

Lucinid bivalves dominate the infauna of tropical seagrass sediments. While the effect of seagrass on lucinids has been studied, the reverse effect has largely been ignored. Lucinids can alter porewater chemistry (i.e., increase porewater nutrients by suspension feeding and decrease porewater sulfides by oxygen introduction and bacterial oxidation), which can potentially change seagrass productivity and growth morphology. To observe correlations between porewater chemistry and lucinid presence, a field survey and laboratory microcosm experiment were conducted. Survey sampling sites with lucinids had significantly lower sulfide and higher ammonium concentrations than sampling sites without lucinids. There was no difference in phosphate concentration among sampling sites. Both lucinid species used in the microcosm experiment (Ctena orbiculata andLucinesca nassula) significantly lowered sulfide concentrations in the sediment porewater. Microcosm and field survey results were incorporated into a sulfide budget. In seagrass sediments, lucinids remove 2–16% of the total sulfide produced. Sulfide is a major stressor to both plants and animals in Florida Bay sediments; this removal may be important to maintaining seagrass productivity and health. Oxygen introduction into sediments byC. orbiculata was estimated in a dye experiment.C. orbiculata were added to small tubes containing sieved mud and incubated in a bath of seawater with a Rhodamine WT. Rhodamine WT accumulation in the sediment was measured. A first order estimate showed that oxygen introduction can account for less than 5% ofC. orbiculata sulfide removal.  相似文献   

Roughness control on hydraulic conductivity in fractured rocks   总被引：1，自引：0，他引：1  

Laura Scesi  Paola Gattinoni 《Hydrogeology Journal》2007,15(2):201-211

The influence of joint roughness on the typologies of fluid flow inside fractures is well known and, thanks to experiences in the field of hydraulics, it has been studied from both a physical and mathematical point of view. Nevertheless, the formulations adopted by traditional hydraulic models are hardly applicable in the geological field, because of the difficulty encountered in the roughness parameter estimation. Normally this parameter can be estimated using the joint roughness coefficient (JRC), which considers both the asperity height and its regularity and directional trend. The main advantage in using the JRC arises from the fact that it can easily be obtained from geological-technical surveys and from comparison with the standard Barton profiles. Some relationships have been built up that allow for the estimation of the hydraulic conductivity tensor (an essential parameter for understanding water flow in fractured rock masses), not only as a function of traditional parameters like aperture, spacing, dip and dip direction, etc., but also of joint roughness, precisely expressed in terms of the roughness coefficient. These relationships have been studied initially from a theoretical point of view and then practically, through laboratory investigations.

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Resumen  Se conoce muy bien la influencia de la rugosidad de las grietas en las tipologías del flujo de fluidos a lo interior de las fracturas y gracias a las experiencias en el campo de hidráulica ha sido posible estudiarla desde puntos de vista matemáticos y físicos. Sin embargo, las formulaciones adoptadas por los modelos hidráulicos tradicionales tienen poca aplicabilidad en el campo geológico debido a la dificultad relacionada con la estimación del parámetro de rugosidad. Normalmente este parámetro puede estimarse usando el coeficiente de rugosidad de grieta (JRC) el cual considera tanto la altura de la aspereza como su regularidad y tendencia direccional. La principal ventaja de utilizar el JRC se deriva del hecho que puede obtenerse fácilmente de levantamientos técnico-geológicos y de la comparación con los perfiles Standard Barton. Se han construido algunas relaciones que permiten la estimación del tensor de conductividad hidráulica (un parámetro esencial para el entendimiento del flujo de agua en masas de roca fracturadas), no solo en función de parámetros tradicionales como apertura, espaciado, buzamiento y dirección de buzamiento, etc., sino también en función de la rugosidad de la grieta estimada con precisión en términos del coeficiente de rugosidad. Estas relaciones se han estudiado inicialmente desde un punto de vista teórico y luego de modo práctico a través de investigaciones de laboratorio.

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Résumé  L’influence de la rugosité des joints sur les types d’écoulement de fluide dans les fractures est bien connue et a été étudiée aussi bien du point de vue physique que mathématique grace à des expériences menées dans le domaine de l’hydraulique. Cependant les formulations adoptées dans les modèles hydrauliques traditionnels sont difficilement applicables dans le domaine de la géologie à cause de la difficulté rencontrée pour estimer la rugosité. Ce paramètre peut normalement être apprécié grace au coefficient de rugosité du joint (JRC), lequel prend en compte à la fois la hauteur de l’aspérité ainsi que sa régularité et sa direction. Le principal avantage dans l’utilisation du JRC réside dans le fait qu’il peut facilement être obtenu à partir d’études techniques-géologiques et par comparaison avec la classification de Barton. Des relations qui permettent une estimation du tenseur de conductivité hydraulique (un paramètre essentiel pour comprendre l’écoulement de l’eau dans les masses rocheuses fracturées) ont été élaborées, pas seulement en fonction de paramètres traditionnels tels que l’ouverture, l’espacement, l’inclinaison et la direction d’inclinaison, etc , mais aussi en prenant en compte la rugosité des joints à travers le coefficient de rugosité. Ces relations ont initialement été étudiées d’un point de vue théorique puis expérimentalement à travers des recherches en laboratoire.

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Spatio-temporal characteristics of small-scale wave–current ripples on the Ameland ebb-tidal delta     

Laura Brakenhoff  Maarten Kleinhans  Gerben Ruessink  Maarten van der Vegt 《地球表面变化过程与地形》2020,45(5):1248-1261

Ebb-tidal deltas are highly dynamic environments affected by both waves and currents that approach the coast under various angles. Among other bedforms of various scales, these hydrodynamics create small-scale bedforms (ripples), which increase the bed roughness and will therefore affect hydrodynamics and sediment transport. In morphodynamic models, sediment transport predictions depend on the roughness height, but the accuracy of these predictors has not been tested for field conditions with strongly mixed (wave–current dominated) forcing. In this study, small-scale bedforms were observed in the field with a 3D Profiling Sonar at five locations on the Ameland ebb-tidal delta, the Netherlands. Hydrodynamic conditions ranged from wave dominated to current dominated, but were mixed most of the time. Small-scale ripples were found on all studied parts of the delta, superimposed on megaripples. Even though a large range of hydrodynamic conditions was encountered, the spatio-temporal variations in small-scale ripple dimensions were relatively small (height 0.015 m, length 0.11 m). Also, the ripples were always highly three-dimensional. These small dimensions are probably caused by the fact that the bed consists of relatively fine sediment. Five bedform height predictors were tested, but they all overestimated the ripple heights, partly because they were not created for small grain sizes. Furthermore, the predictors all have a strong dependence on wave- and current-related velocities, whereas the ripple heights measured here were only related to the near-bed orbital velocity. Therefore, ripple heights and lengths in wave–current-dominated, fine-grained coastal areas ( mm) may be best estimated by constant values rather than values dependent on the hydrodynamics. In the case of the Ameland ebb-tidal delta, these values were found to be m and m. ©2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Contrasting patterns of precipitation seasonality during the Holocene in the south‐ and north‐central Mediterranean     

Michel Magny  Odile Peyron  Laura Sadori  Elena Ortu  Giovanni Zanchetta  Boris Vannière  Willy Tinner 《第四纪科学杂志》2012,27(3):290-296

Pollen‐based quantitative estimates of seasonal precipitation from Lake Pergusa and lake‐level data from Lake Preola in Sicily (southern Italy) allow three successive periods to be distinguished within the Holocene: an early Holocene period before ca. 9800 cal a BP with rather dry climate conditions in winter and summer, a mid‐Holocene period between ca. 9800 and 4500 cal a BP with maximum winter and summer wetness, and a late Holocene period after 4500 cal a BP with declining winter and summer wetness. This evolution observed in the south‐central Mediterranean shows strong similarities to that recognized in the eastern Mediterranean. But, it contrasts with that reconstructed in north‐central Italy, where the mid‐Holocene appears to be characterized by a winter (summer) precipitation maximum (minimum), while the late Holocene coincided with a decrease (increase) in winter (summer) precipitation. Maximum precipitation at ca. 10 000–4500 cal a BP may have resulted from (i) increased local convection in response to a Holocene insolation maximum at 10 000 cal a BP and then (ii) the gradual weakening of the Hadley cell activity, which allowed the winter rainy westerlies to reach the Mediterranean area more frequently. After 4500 cal a BP, changes in precipitation seasonality may reflect non‐linear responses to orbitally driven insolation decrease in addition to seasonal and inter‐hemispheric changes of insolation. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Thermal bending of thin, anisotropic, clamped elliptic plates     

P.A.A Laura  C.A Rossit 《Ocean Engineering》1998,26(5):485-488

The present note deals with the exact analytical solution of thermal bending of clamped, anisotropic, elliptic plates in the case where the thermal field is given by an expression of the type T(x,y,z)=z(Ax²+Cxy+By²).The problem is of basic interest in some ocean and mechanical structural systems since anisotropic materials are commonly used in those fields. Obviously the case of an orthotropic material constitutes a particular situation of the problem under study.  相似文献   

Trace element and molecular markers of organic carbon dynamics along a shelf–basin continuum in sediments of the western Arctic Ocean     

Laura L. Belicka  Robie W. Macdonald  H. Rodger Harvey 《Marine Chemistry》2009,115(1-2):72-85

Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.  相似文献   

Impact of wildfire on source water contributions in Devil Creek,CA: evidence from end‐member mixing analysis     

Helen Y. Jung  Terri S. Hogue  Laura K. Rademacher  Tom Meixner 《水文研究》2009,23(2):183-200

A geochemical and end‐member mixing analysis (EMMA) is undertaken in Devil Canyon catchment, located in southern California, to further understanding of watershed behaviour and source water contributions after an acute and extensive wildfire. Physical and chemical transformations in post‐fire watersheds are known to increase overland flow and decrease infiltration, mainly due to formation of a hydrophobic layer at, or near, the soil surface. However, less is known about subsurface flow response in burned watersheds. The current study incorporates EMMA to evaluate and quantify source water contributions before, and after, a catchment affected by wildfires in southern California during the fall of 2003. Pre‐ and post‐fire stream water data were available at several sampling sites within the catchment, allowing the identification of contributing water sources at varying spatial scales. Proposed end‐member observations (groundwater, overland flow, shallow subsurface flow) were also collected to constrain and develop the catchment mixing model. Post‐fire source water changes are more evident in the smaller and faster responding sub‐basin (interior sampling point). Early post‐fire storm events are dominated by overland flow with no significant soil water or groundwater flow contribution. Inter‐storm streamwater in this smaller basin shows an increase in groundwater and a decrease in soil water. In the larger, baseflow‐dominated system, source water components appear less affected by fire. A slight increase in lateral flow is observed with only a slight decrease in baseflow. Changes in the post‐fire flow regimes affect nutrient loading and chemical response of the basin. Relatively rapid recovery of the chaparral ecosystem is evidenced, with active re‐growth and evapotranspiration evidenced by the fourth post‐fire rainy season. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Photochemical changes in chemical markers of sedimentary organic matter source and age     

Lawrence M. Mayer  Linda L. Schick  Thomas S. Bianchi  Laura A. Wysocki 《Marine Chemistry》2009,113(1-2):123-128

Several chemical markers of organic matter source and age are shown to be susceptible to light-induced alteration. To test for the photochemical lability of markers previously employed for sediments from the Louisiana coastal zone, we subjected sediments under resuspension conditions to simulated sunlight, and monitored changes in C:N and Br:OC ratios, δ¹³C, Δ¹⁴C, and lignin composition. Markers of terrigenous origin (high C:N, lignin) decreased and δ¹³C became enriched in sediments containing primarily terrigenous organic matter, while a marker of marine organic matter (Br:OC) decreased in samples containing significant contributions from this source. Preferential loss of ¹⁴C from all sediments indicated enhanced photochemical lability of organic matter of relatively recent origin, consistent with the changes in chemical markers. Most, but not all, experimental alterations are consistent with field distributions of these markers. Relatively small experimental changes in the markers in combination with confounding processes in the environment, however, prevent these parallel trends from providing any more than a consistency test for the importance of photochemical reactions in this region.  相似文献   

Macrofaunal density and biomass in the Campeche Canyon, Southwestern Gulf of Mexico     

Elva Escobar Briones  Erika Laura Estrada Santilln  Pierre Legendre 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(24-26):2679

The composition, density and community structure of the benthic macrofauna were investigated in sediments of the Campeche Canyon in the SW Gulf of Mexico. Total macrofaunal density ranged from 9466±2736 ind m⁻² at the continental shelf station to 1550±195 ind m⁻² in the canyon. Density values significantly diminished with distance from the coast and depth; only a few stations in the center of the canyon displayed larger density values (E-37 with 4666±1530 ind m⁻², E-36 with 5791±642 ind m⁻² and E-26 with 6925±2258 ind m⁻²). Densities were positively correlated to organic nitrogen in the sediment (r=0.82) and coarse silt (r=0.43), and negatively with depth (r=−0.74) and distance from the coast (r=−0.68). At all stations, the polychaete worms contributed most to the multi-species community structure. The nematodes and Foraminifera displayed their highest densities in the center of the canyon. The biomass values declined significantly with depth. We conclude that the macrofauna density and biomass changed in response to organic matter contents in the sediment, both with distance from the coast and with depth.  相似文献